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- Title
Catalytic CO Oxidation by O<sub>2</sub> Mediated by Noble‐Metal‐Free Cluster Anions Cu<sub>2</sub>VO<sub>3<bold>–</bold>5</sub><sup>−</sup>.
- Authors
Wang, Li‐Na; Li, Xiao‐Na; Jiang, Li‐Xue; Yang, Bin; Liu, Qing‐Yu; Xu, Hong‐Guang; Zheng, Wei‐Jun; He, Sheng‐Gui
- Abstract
Abstract: Catalytic CO oxidation by molecular O2 is an important model reaction in both the condensed phase and gas‐phase studies. Available gas‐phase studies indicate that noble metal is indispensable in catalytic CO oxidation by O2 under thermal collision conditions. Herein, we identified the first example of noble‐metal‐free heteronuclear oxide cluster catalysts, the copper–vanadium bimetallic oxide clusters Cu2VO3–5− for CO oxidation by O2. The reactions were characterized by mass spectrometry, photoelectron spectroscopy, and density functional calculations. The dynamic nature of the Cu−Cu unit in terms of the electron storage and release is the driving force to promote CO oxidation and O2 activation during the catalysis.
- Subjects
CARBON monoxide; CATALYSIS; CONDENSED matter; GAS phase reactions; COPPER compounds; BIMETALLIC catalysts
- Publication
Angewandte Chemie, 2018, Vol 130, Issue 13, p3407
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201712129