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- Title
Basic and Coordination Properties of Tetraphenylporphine Derivatives.
- Authors
Ivanova, Yu. B.; Plotnikova, A. O.; Semeikin, A. S.; Pukhovskaya, S. G.; Mamardashvili, N. Zh.
- Abstract
Basic and coordination properties of 5,10,15,20-tetrakis(3,5-dibromophenyl)porphine and 5,10,15,20-tetrakis(4-methoxy-3-bromophenyl)porphine in acetonitrile have been investigated by means of spectrophotometry. The optimization of the geometry parameters of polysubstituted porphyrins has been performed using quantum-chemical method (РМ3). The relationship between geometric structure of the studied porphyrins and their coordination, basic, and spectral properties is discussed.
- Subjects
PHENYL compounds; PORPHYRINS; COORDINATION compounds; PROTON transfer reactions; X-ray diffraction
- Publication
Russian Journal of General Chemistry, 2018, Vol 88, Issue 10, p2103
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363218100122