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- Title
Solvent effect on the acidity constants of lignin-related phenols in water-acetone and water-1,4-dioxane binary mixtures within the Kamlet-Taft formalism.
- Authors
Shorina, N.; Kosyakov, D.; Bogolitsyn, K.; Gorbova, N.
- Abstract
Multiparameter regression analysis combined with the principle of liner solvation energies relationship was applied to assess the solvent effect on the acidity of the lignin-related phenols in water-dioxane and water-acetone systems. The coefficients a, b, and s of the Kamlet-Taft equation were calculated taking into account the contributions of different types of solute-solvent interactions to the protolytic properties of the phenols of the guaiacol series.
- Subjects
SOLVENTS; ACIDITY; LIGNINS; PHENOLS; BINARY mixtures; DIOXANE; REGRESSION analysis
- Publication
Russian Journal of General Chemistry, 2012, Vol 82, Issue 12, p1909
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S107036321212002X