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- Title
Reaction of the System Arene(Hetarene)thiol-Diselenide with Phenylacetylene.
- Authors
Papernaya, L. K.; Albanov, A. I.; Sukhomazova, E. N.; Levanova, E. P.; Deryagina, E. N.
- Abstract
Liquid-phase thermal reactions of phenylacetylene with the system arene(hetarene)thioldiselenide at 110-180°C proceed through conjugate addition to the phenylacetylene triple bond of one alkylselanyl and one arene(hetarenesulfanyl groups to form 2-alkylselanyl-2-[aryl(hetaryl)sulfanyl]-1-phenylethenes and 1-alkylselanyl-2-[aryl(hetaryl)sulfanyl]-1-phenylethenes. Therewith, direct addition of thiols to phenylacetylene slows down.
- Subjects
CHEMICAL reactions; CHEMICAL processes; CHEMISTRY; PHENYLACETATES
- Publication
Russian Journal of General Chemistry, 2004, Vol 74, Issue 5, p708
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1023/B:RUGC.0000039083.59169.f3