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- Title
Multi‐electron Oxidation of Ce(III) Complexes Facilitated by Redox‐Active Ligands.
- Authors
Rupasinghe, D. M. Ramitha Y. P.; Lopez, Lauren M.; Poore, Andrew T.; Baxter, Makayla R.; Lin, Nathan J.; Mitchell, Andrew W.; Zeller, Matthias; Tian, Shiliang; Bart, Suzanne C.
- Abstract
A family of cerium complexes featuring a redox‐active ligand in different oxidation states has been synthesized, including the the iminosemiquinone (isq)1− compound, Ce(dippisq)3 (1‐Ceisq), and the amidophenolate (ap)2− species CeIII(dippap)3K3 (2‐Ceap), [CeIII(dippap)3K][K(18‐c‐6)]2 (2‐Ceap 18c6), and [CeIII(dippap)3K][K(15‐c‐5)2]2 (2‐Ceap 15c5). Treating 2‐Ceap 15c5 with dioxogen furnishes the cerium(IV) derivative [CeIV(dippap)3][K(15‐c‐5)2]2 (3‐Ceap 15c5), and an analogous synthesis can be used to generate [CeIV(dippap)3][K(crypt)]2 (3‐Ceap crypt). Similarly, addition of hexamethyldisiloxane produces an interesting bis(amidophenolate) species, [(Me3SiO)2CeIV(dippap)2][K(15‐c‐5)2]2 (4‐CeOSiMe3). Full spectroscopic and structural characterization of each derivative was performed to establish the oxidation states of both the ligands and the cerium ions.
- Subjects
LIGANDS (Chemistry); OXIDATION states; CERIUM
- Publication
European Journal of Inorganic Chemistry, 2024, Vol 27, Issue 12, p1
- ISSN
1434-1948
- Publication type
Article
- DOI
10.1002/ejic.202300761