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- Title
Synthesis of Novel Chiral Diamino Alcohols and Their Application in Copper-Catalyzed Asymmetric Allylic Oxidation of Cycloolefins.
- Authors
Faraji, Laleh; Samadi, Saadi; Jadidi, Khosrow; Notash, Behrouz
- Abstract
The small library of new enantiomerically pure (S,S)-diamino alcohols 1 and their hydroxyldiamide precursors 2 were conveniently synthesized on a gram scale from inexpensive and commercially chiral pool amino acids. The catalytic and induced asymmetric effects of the chiral ligands 1 in the asymmetric allylic oxidation of cycloolefins were investigated.
- Subjects
CHEMICAL synthesis; DIAMINO amino acids; CYCLOALKENES; AMINO acids; ALLYL alcohol
- Publication
Bulletin of the Korean Chemical Society, 2014, Vol 35, Issue 7, p1989
- ISSN
0253-2964
- Publication type
Article
- DOI
10.5012/bkcs.2014.35.7.1989