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- Title
Rhodium-Catalyzed Directed Sulfenylation of Arene CH Bonds.
- Authors
Yang, Yaxi; Hou, Wei; Qin, Lihuai; Du, Juanjuan; Feng, Huijin; Zhou, Bing; Li, Yuanchao
- Abstract
The rhodium-catalyzed intermolecular direct CH thiolation of arenes with aryl and alkyl disulfides was developed for the first time to provide a convenient route to aryl thioethers. This strategy is compatible with many different directing groups and exhibits excellent functional group tolerance. More significantly, mono- or dithiolation can be selectively achieved, thus providing a straightforward way for selective preparation of aryl thioethers and dithioethers.
- Subjects
RHODIUM catalysts; AROMATIC compounds; ARYL group; ALKYL compounds; SULFIDES
- Publication
Chemistry - A European Journal, 2014, Vol 20, Issue 2, p416
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201303730