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- Title
Base-Stabilized Boryl and Cationic Haloborylene Complexes of Iron.
- Authors
Bissinger, Philipp; Braunschweig, Holger; Damme, Alexander; Dewhurst, Rian D.; Kraft, Katharina; Kramer, Thomas; Radacki, Krzysztof
- Abstract
The synthesis of base-stabilized boryl and borylene complexes is reported. An N-heterocyclic carbene (NHC)-stabilized iron-dihydroboryl complex was prepared by two different routes including methane liberation and salt elimination. A range of base-stabilized iron-dichloroboryl complexes was prepared by addition of Lewis bases to boryl complexes. Base-stabilized, cationic monochloroborylene complexes were synthesized from these boryl complexes by halide abstraction by using weakly coordinating anions.
- Subjects
CHEMICAL synthesis; LEWIS acids; HALIDES; CARBENES; CARBON compounds
- Publication
Chemistry - A European Journal, 2013, Vol 19, Issue 40, p13402
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201302263