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- Title
Achieving Vinylic Selectivity in Mizoroki-Heck Reaction of Cyclic Olefins.
- Authors
Wu, Xiaojin; Lu, Yunpeng; Hirao, Hajime; Zhou, Jianrong (Steve)
- Abstract
In Heck reactions of cyclic olefins, the products usually have aryl groups that end up at the allylic and/or homoallylic position. We herein report new selectivity that adds aryl groups to the vinylic position. Cyclic olefins of various ring size worked well. The desired isomers were produced by palladium-hydride-catalyzed isomerization of the initial products. Thus, a specific catalyst must be used so that it can perform two jobs under one set of reaction conditions.
- Publication
Chemistry - A European Journal, 2013, Vol 19, Issue 19, p6014
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201204427