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- Title
Synthesis of Poly(N‐vinylamide)s and Poly(vinylamine)s and Their Block Copolymers by Organotellurium‐Mediated Radical Polymerization.
- Authors
Fan, Weijia; Yamago, Shigeru
- Abstract
Controlled polymerization of acyclic N‐vinylamides, that is, N‐methyl‐N‐vinylacetamide (NMVA), N‐vinylacetamide (NVA), and N‐vinylformamide (NVF), by organotellurium‐mediated radical polymerization (TERP) is reported. The corresponding poly(N‐vinylamide)s with controlled molecular weight and low dispersity (Ð<1.25) were obtained with high monomer conversion in all cases. This is the first report on the controlled polymerization of NVF. Hydrolysis of the polymers, in particular PNVF, occurred quantitatively under mild reaction conditions, giving structurally controlled poly(vinylamine)s. Block copolymers containing poly(N‐vinylamide) and poly(vinylamine) segments were also synthesized in a controlled manner.
- Subjects
POLYMERIZATION; ORGANOTELLURIUM compounds; COPOLYMERS; POLYMERS; HYDROLYSIS
- Publication
Angewandte Chemie, 2019, Vol 131, Issue 21, p7187
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201902940