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- Title
Synthesis of meso-tetraarylporphyrins using hafnium (IV) bis(perfluorooctanesulfonyl)imide complex in perfluorodecalin medium.
- Authors
Hong, Mei; Yan, Junmin
- Abstract
This letter presents a non-conventional synthesis of meso-porphyrins in moderate yields, using catalytic quantities of hafnium (IV) bis(perfluorooctanesulfonyl)imide complex in a perfluorodecalin biphasic system. Various meso-tetraarylporphyrins were obtained in good yields. The catalyst is selectively dissolved in perfluorodecalin, and can be recovered simply by phase separation and reused several times without any obvious decrease of activity.
- Subjects
CHEMICAL derivatives; PORPHYRINS; HAFNIUM compounds; OCTANE; SULFONYL compounds; IMIDES; DECAHYDRONAPHTHALENE; CATALYTIC activity
- Publication
Journal of Chemical Research, 2016, Vol 40, Issue 9, p549
- ISSN
1747-5198
- Publication type
Article
- DOI
10.3184/174751916X14718751882863