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- Title
Utilizing a Metal Melt of Gallium for the Synthesis of the Homoleptic 1, 2,4-Triazolate Dense Framework <sup>3</sup><sub>∞</sub>[Ga(Tz)<sub>3</sub>].
- Authors
Rybak, Jens‐Christoph; Rekawka, Adam; Müller‐Buschbaum, Klaus
- Abstract
The low melting element gallium was utilized as a metal melt together with the azole 1, 2,4,- 1H-triazole for the synthesis of the homoleptic framework 3∞[Ga(Tz)3], Tz- = 1, 2,4-triazolate. The framework is formed at 180 °C at the phase border of two liquid phases, gallium and the azole, which do not mix with one another. Thus, 1, 2,4,- 1H-triazole is also in molten state. The homoleptic triazolate adopts the CoAs3 structure and a (4, 6) net topology, exhibiting good thermal stability of 440 °C.
- Subjects
GALLIUM isotopes; HOMOLEPTIC compounds; MOLECULAR structure of azoles; THERMAL stability; CRYSTAL structure
- Publication
Zeitschrift für Anorganische und Allgemeine Chemie, 2013, Vol 639, Issue 14, p2382
- ISSN
0044-2313
- Publication type
Article
- DOI
10.1002/zaac.201300401