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- Title
Reversible Hydrophobic-Hydrophilic Transition of Ionic Liquids Driven by Carbon Dioxide.
- Authors
Xiong, Dazhen; Cui, Guokai; Wang, Jianji; Wang, Huiyong; Li, Zhiyong; Yao, Kaisheng; Zhang, Suojiang
- Abstract
Ionic liquids (ILs) with a reversible hydrophobic-hydrophilic transition were developed, and they exhibited unique phase behavior with H2O: monophase in the presence of CO2, but biphase upon removal of CO2 at room temperature and atmospheric pressure. Thus, coupling of reaction, separation, and recovery steps in sustainable chemical processes could be realized by a reversible liquid-liquid phase transition of such IL-H2O mixtures. Spectroscopic investigations and DFT calculations showed that the mechanism behind hydrophobic-hydrophilic transition involved reversible reaction of CO2 with anion of the ILs and formation of hydrophilic ammonium salts. These unique IL-H2O systems were successfully utilized for facile one-step synthesis of Au porous films by bubbling CO2 under ambient conditions. The Au porous films and the ILs were then separated simultaneously from aqueous solutions by bubbling N2, and recovered ILs could be directly reused in the next process.
- Subjects
IONIC liquids; HYDROPHILIC interactions; CARBON dioxide; SUSTAINABLE chemistry; COUPLING reactions (Chemistry)
- Publication
Angewandte Chemie International Edition, 2015, Vol 54, Issue 25, p7265
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201500695