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- Title
Miscibility and shape memory property of poly(vinyl chloride)/thermoplastic polyurethane blends.
- Authors
Han Mo Jeong; Ji Hun Song; Sang Yoon Lee; Byung Kyu Kim
- Abstract
The miscibility and the shape memory effect of PVC blends with segmented thermoplastic polyurethanes (TPUs), synthesized from diol-terminated polycaprolactone (PCL), hexamethylene diisocyanate, 4,4′-dihydroxy biphenyl, were studied. PVC was miscible with PCL segment in TPU and the glass transition temperature of this miscible amorphous domain varied smoothly with composition. When PVC was blended with TPU by the weight ratio of 8/2, the hysterisis in repeated cyclic tensile test was reduced compared with PVC. However, in 6/4 blends, unrecoverable permanent deformation was increased compared with PVC. Dynamic mechanical properties were examined to explain these results.
- Subjects
POLYVINYL chloride; POLYURETHANES; MISCIBILITY; SHAPE memory effect; HEXAMETHYLENE diisocyanate; DEFORMATIONS (Mechanics)
- Publication
Journal of Materials Science, 2001, Vol 36, Issue 22, p5457
- ISSN
0022-2461
- Publication type
Article
- DOI
10.1023/A:1012481631570