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- Title
Crystal structure of bis((N-methyl-2-oxyethyl)amine)-bis(μ<sub>2</sub>-N,N,N-tris(2-oxoethyl)amine)-bis(isopropoxy)-bis(μ<sub>3</sub>-oxo)tetratitanium(IV)– isopropanol (1/2), C<sub>34</sub>H<sub>76</sub>N<sub>4</sub>O<sub>16</sub>Ti<sub>4</sub>
- Authors
Youzhu, Yu; Hui, Wang; Leilei, Li; Yuhua, Guo; Qianqian, Fu; Jingtao, Dai
- Abstract
In the crystal structure, there are two Ti SP 4+ sp ions, one I i SB 3 sb -O, one MDEOA, one TEOA and one isopropoxide groups (the figure), and as well one solvent of iPrOH was observed in the asymmetric unit of the structrue. Both the two MDEOA ligands adopt I i SB 1 sb - I i SP 1 sp : I i SP 1 sp : I i SP 1 sp coordination mode, while the two TEOA present I i SB 2 sb - I i SP 1 sp : I i SP 1 sp : I i SP 1 sp : I i SP 2 sp mode. All the Ti SP 4+ sp ions show octahedral TiO SB 5 sb N coordination environments which were connected by two I i SB 3 sb -O atoms and two I i SB 2 sb -O atoms from ligands TEOA to generate the Ti SB 4 sb core via edge-sharing mode.
- Subjects
CRYSTAL structure; MOLECULAR structure; SOLAR ultraviolet radiation; BAND gaps; ISOPROPYL alcohol; METALLIC oxides
- Publication
Zeitschrift für Kristallographie / New Crystal Structures, 2022, Vol 237, Issue 5, p965
- ISSN
1433-7266
- Publication type
Article
- DOI
10.1515/ncrs-2022-0325