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- Title
One‐Pot Synthesis of Diverse 1,4‐[60]Fullerephenols via Three‐Component Umpolung Cascade Coupling of Phenols, C<sub>60</sub>, and Nucleophiles.
- Authors
Zhang, Jun‐Xiang; Wu, Yuan‐Ze; Chen, Dong‐Mei; Xuan, Jun; Li, Fei
- Abstract
A three‐component umpolung cascade coupling reaction of phenols, C60, and different nucleophiles which includes H2O, alcohols, triphenylamines and carbazoles was developed. Furthermore, one‐pot 1,4‐bisphenol coupling on C60 has been realized by this method. This practical protocol features high chemo‐ and regioselectivity, wide substrate range, easy operation and low cost, thus providing a robust method for the one‐pot synthesis of various unsymmetrical 1,4‐[60]fullerephenols.
- Subjects
NUCLEOPHILES; UMPOLUNG; PHENOLS; PHENOL; ALCOHOL; CARBAZOLE
- Publication
Chemistry - A European Journal, 2023, Vol 29, Issue 35, p1
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.202300391