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- Title
Exo- Dig Radical Cascades of Skipped Enediynes: Building a Naphthalene Moiety within a Polycyclic Framework.
- Authors
Pati, Kamalkishore; Hughes, Audrey M.; Phan, Hoa; Alabugin, Igor V.
- Abstract
Cascade radical transformations of acyclic precursors open efficient, convenient and atom-economical access to functionalized compounds of increased structural complexity. This report describes a selective sequence of 5- exo- dig and 6- exo- dig cyclizations followed by attack at a pendant aromatic moiety and rearomatization.
- Subjects
ENEDIYNES; NAPHTHALENE; POLYCYCLIC aromatic compounds; MOIETIES (Chemistry); ANTINEOPLASTIC antibiotics
- Publication
Chemistry - A European Journal, 2014, Vol 20, Issue 2, p390
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201304092