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- Title
Transformation of RN=CHPh to R(R′<sub>3</sub>Si)NCH<sub>2</sub>Ph in the Catalytic Desulfurization of Secondary Thioamide with R′<sub>3</sub>SiH Promoted by an Iron Complex.
- Authors
Fukumoto, Kozo; Sakai, Akane; Murai, Toshiaki; Nakazawa, Hiroshi
- Abstract
ABSTRACT The reaction of imine (RN=CHPh) with hydrosilane (R′3SiH) in the presence of CpFe(CO)2Me ( 1) revealed the formation of a hydrosilylation product (R(R′3Si)NCH2Ph). The findings helped us to understand the reaction mechanism of desulfurization of secondary thioamide catalyzed by 1 to give the corresponding imine and amine as a major and minor product, respectively.
- Subjects
THIOAMIDES; IRON; IMINES; HYDROSILYLATION; AMINE imides
- Publication
Heteroatom Chemistry, 2014, Vol 25, Issue 6, p607
- ISSN
1042-7163
- Publication type
Article
- DOI
10.1002/hc.21175