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- Title
Aqueous DMSO Mediated Conversion of (2-(Arylsulfonyl)vinyl)iodonium Salts to Aldehydes and Vinyl Chlorides.
- Authors
Zawia, Eman; Moran, Wesley J.
- Abstract
Vinyl(aryl)iodonium salts are useful compounds in organic synthesis but they are under-utilized and their chemistry is under-developed. Herein is described the solvolysis of some vinyl(phenyl)iodonium salts, bearing an arylsulfonyl group, in aqueous DMSO leading to aldehyde formation. This unusual process is selective and operates under ambient conditions. Furthermore, the addition of aqueous HCl and DMSO to these vinyl(aryl)iodonium salts allows their facile conversion to vinyl chlorides.
- Subjects
VINYL chloride; ALDEHYDE analysis; DIMETHYL sulfoxide; NITRILIMINES; ORGANIC synthesis
- Publication
Molecules, 2016, Vol 21, Issue 8, p1073
- ISSN
1420-3049
- Publication type
Article
- DOI
10.3390/molecules21081073