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- Title
Crystal structures of [ M(Еn)](ReO) ( M = Ni, Zn).
- Authors
Khranenko, S.; Bykova, E.; Zadesenets, A.; Gromilov, S.
- Abstract
The structures of two isostructural phases of [ M(Еn)](ReO) ( M = Ni, Zn; Еn is ethylenediamine) are studied. The crystal structures belong to the triclinic system, but demonstrate a pseudohexagonal packing motif. It is shown that the product of thermal decomposition of [Zn(Еn)](ReO) (hydrogen atmosphere, 400 °C) is a homogeneous mixture of nanocrystalline zinc and rhenium powders with coherent scattering regions of ~30 nm.
- Subjects
CRYSTAL structure; COHERENT scattering; NANOCRYSTALS; RHENIUM; ZINC
- Publication
Journal of Structural Chemistry, 2017, Vol 58, Issue 1, p90
- ISSN
0022-4766
- Publication type
Article
- DOI
10.1134/S0022476617010139