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- Title
Crystal structure of [Co(N<sub>2</sub>C<sub>2</sub>H<sub>8</sub>)<sub>3</sub>] [AuBr<sub>4</sub>]<sub>2</sub>Br bis(tetrabromoaurate(III)) tris(ethylenediamine) cobalt(III) bromide.
- Authors
Baidina, I. A.; Makotchenko, E. V.
- Abstract
A double complex salt [Co(N2C2H8)3][AuBr4]2Br is obtained and characterized using single crystal X-ray diffraction analysis. The crystallographic data of C6H24Au2Br9CoN6 are as follows: a = 21.6479(17) Å, b = 14.9085(12) Å, c = 8.2676(7) Å, β = 110.820(2)°, V = 1538.92(12) Å3, C2/c space group, Z = 4, dx = 3.602 g/cm3. Square planar coordination of the gold atom in the complex anion is completed to a tetragonal pyramid by an additional bromine atom of the adjacent complex anion at the Au... Br distance of 3.677 Å.
- Subjects
ETHYLENEDIAMINE; X-ray diffraction; BROMINE; ANIONS; COBALT
- Publication
Journal of Structural Chemistry, 2010, Vol 51, Issue 1, p187
- ISSN
0022-4766
- Publication type
Article
- DOI
10.1007/s10947-010-0028-9