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- Title
Crystal structure of [(C<sub>5</sub>Me<sub>4</sub>Et)<sub>3</sub>Rh<sub>3</sub>(μ<sub>3</sub>-Se)<sub>2</sub>](PF<sub>6</sub>)<sub>2</sub>CH<sub>3</sub>CN and [(C<sub>5</sub>Me<sub>4</sub>Et)<sub>2</sub>Rh<sub>2</sub>(μ<sub>2</sub>-Cl)<sub>3</sub>]PF<sub>6</sub>
- Authors
Abramov, P. A.; Sokolov, M. N.; Virovets, A. V.; Fedin, V. P.
- Abstract
The crystal structure of [(C5Me4Et)3Rh3(μ3-Se)2](PF6)2 and [(C5Me4Et)2Rh2(μ2-Cl)3]PF6, obtained in the reaction of [(C5Me4Et)Rh(C6H6)](PF6)2 with ZnSe in 4M HCl under hydrothermal conditions, is determined. In agreement with the 18VE rule, the triangular cluster contains single metal-metal bonds (Rh-Rh 2.864(1) Å), whereas they are absent in the binuclear complex (Rh ...Rh 3,216(1) Å).
- Subjects
CHEMICAL structure; PHYSICAL &; theoretical chemistry; CHEMICAL reactions; METAL-metal bonds; CHEMICAL bonds; CLUSTERING of particles
- Publication
Journal of Structural Chemistry, 2009, Vol 50, Issue 1, p162
- ISSN
0022-4766
- Publication type
Article
- DOI
10.1007/s10947-009-0022-2