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- Title
Multi-Functional Potassium Ion Assists Ammonium Vanadium Oxide Cathode for High-Performance Aqueous Zinc-Ion Batteries.
- Authors
He, Dan; Sun, Tianjiang; Wang, Qiaoran; Ma, Tao; Zheng, Shibing; Tao, Zhanliang; Liang, Jing
- Abstract
Ammonium vanadium oxide (NH4V4O10) is a promising layered cathode for aqueous zinc-ion batteries owing to its high specific capacity (>300 mA h g−1). However, the structural instability causes serious cycling degradation through irreversible insertion/extraction of NH4+. Herein, a new potassium ammonium vanadate Kx(NH4)1−xV4O10 (named KNVO) is successfully synthesized by a one-step hydrothermal method. The inserted of K+ can act as structural pillars, connect the adjacent layers closer and partially reduce the de-insertion of NH4+. Due to the multi-functional of K+, the prepared KNVO presents a high specific discharge capacity of 432 mA h g−1 at a current density of 0.4 A g−1, long cycle stability (2000 cycles, 94.2%) as well as impressive rate performance (200 mA h g−1 at 8 A g−1).
- Subjects
VANADIUM oxide; POTASSIUM ions; AMMONIUM ions; COLUMNS; POTASSIUM channels; CATHODES
- Publication
Batteries, 2022, Vol 8, Issue 8, pN.PAG
- ISSN
2313-0105
- Publication type
Article
- DOI
10.3390/batteries8080084