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- Title
A spin-crossover framework endowed with pore-adjustable behavior by slow structural dynamics.
- Authors
Xue, Jin-Peng; Hu, Yang; Zhao, Bo; Liu, Zhi-Kun; Xie, Jing; Yao, Zi-Shuo; Tao, Jun
- Abstract
Host-guest interactions play critical roles in achieving switchable structures and functionalities in porous materials, but design and control remain challenging. Here, we report a two-dimensional porous magnetic compound, [FeII(prentrz)2PdII(CN)4] (prentrz = (1E,2E)−3-phenyl-N-(4H-1,2,4-triazol-4-yl)prop-2-en-1-imine), which exhibits an atypical pore transformation that directly entangles with a spin state transition in response to water adsorption. In this material, the adsorption-induced, non-uniform pedal motion of the axial prentrz ligands and the crumpling/unfolding of the layer structure actuate a reversible narrow quasi-discrete pore (nqp) to large channel-type pore (lcp) change that leads to a pore rearrangement associated with simultaneous pore opening and closing. The unusual pore transformation results in programmable adsorption in which the lcp structure type must be achieved first by the long-time exposure of the nqp structure type in a steam-saturated atmosphere to accomplish the gate-opening adsorption. The structural transformation is accompanied by a variation in the spin-crossover (SCO) property of FeII, i.e., two-step SCO with a large plateau for the lcp phase and two-step SCO with no plateau for the nqp phase. The unusual adsorption-induced pore rearrangement and the related SCO property offer a way to design and control the pore structure and physical properties of dynamic frameworks. Host-guest interactions can play a critical role in achieving switchable porous materials, but controlling them remains challenging. Here the authors report an atypical pore rearrangement in a magnetic 2D porous framework upon water adsorption; the structural transformation affects the magnetic properties of the material.
- Subjects
POROSITY; POROUS materials; CYANIDES; MAGNETIC materials; SPIN crossover; MAGNETIC properties; STRUCTURAL dynamics
- Publication
Nature Communications, 2022, Vol 13, Issue 1, p1
- ISSN
2041-1723
- Publication type
Article
- DOI
10.1038/s41467-022-31274-8