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- Title
Catalytic Synthesis of Functional Silicon-Stereogenic Silanes through Candida antarctica Lipase B Catalyzed Remote Desymmetrization of Silicon-Centered Diols.
- Authors
Lu, Xing; Li, Li; Yang, Wei; Jiang, Kezhi; Yang, Ke‐Fang; Zheng, Zhan‐Jiang; Xu, Li‐Wen
- Abstract
A series of silicon-containing diols are synthesized and used in lipase-catalyzed remote desymmetrization. This synthetic method is valuable in the construction of optically active silicon-stereogenic organosilicon compounds. Good enantioselectivities of the remote desymmetrization was achieved with Candida antarctica lipase B (CAL-B) (up to 90:10 er).
- Subjects
SILICON spectra; LIPASES; GLYCOL synthesis; ENANTIOSELECTIVE catalysis; ORGANOSILICON compounds; CANDIDA
- Publication
European Journal of Organic Chemistry, 2013, Vol 2013, Issue 26, p5814
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201300932