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- Title
First Water-Soluble Backbone Ru-Ru-Ni Heterometallic Organometallic Polymer.
- Authors
Scalambra, Franco; Serrano‐Ruiz, Manuel; Romerosa, Antonio
- Abstract
The water-soluble backbone heterometallic polymer {[(PTA)2CpRu-μ-CN-RuCp(PTA)2-μ-NiCl3]} n ( 2) is synthesized using a reproducible and robust method and fully characterized by X-ray single crystal diffraction. The Ru-Ru-Ni polymer is found to be stable in the solid state and soluble in water. Nuclear magnetic resonance (NMR) and light scattering studies show that the polymer is stable in water for several days in air.
- Subjects
POLYMER research; RUTHENIUM; METAL complexes; NUCLEAR magnetic resonance; LIGHT scattering
- Publication
Macromolecular Rapid Communications, 2015, Vol 36, Issue 7, p689
- ISSN
1022-1336
- Publication type
Article
- DOI
10.1002/marc.201400657