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- Title
Efficient Solar‐Assisted O<sub>2</sub> Reduction Using a Cofacial Iron Porphyrin Dimer Catalyst Integrated into a p‐CuBi<sub>2</sub>O<sub>4</sub> Photocathode.
- Authors
Mohamed, Eman A.; Zahran, Zaki N.; Haleem, Ashraf Abdel; Naruta, Yoshinori
- Abstract
Abstract: A cofacial iron porphyrin heterodimer, Fe2TPFPP‐TMP showed high electrocatalytic activity, selectivity, and stability for O2 reduction to H2O both in homogeneous non‐aqueous and heterogeneous neutral aqueous solutions. When it is integrated to FTO/p‐CuBi2O4 (FTO=fluorine doped tin oxide) photocathode prepared by a simple novel method, a remarkable efficient solar‐assisted O2 reduction is achieved in neutral potassium phosphate (KPi) or basic NaOH solutions saturated with O2.
- Subjects
IRON porphyrins; PHOTOCATHODES; DIMERS; FLUORINE; SCANNING electron microscopes; FERROCENE
- Publication
Chemistry - A European Journal, 2018, Vol 24, Issue 42, p10606
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201704143