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- Title
Saccharin-Based μ-Oxo Imidoiodane: A Readily Available and Highly Reactive Reagent for Electrophilic Amination.
- Authors
Yoshimura, Akira; Koski, Steven R.; Fuchs, Jonathan M.; Saito, Akio; Nemykin, Victor N.; Zhdankin, Viktor V.
- Abstract
Three new saccharin-based hypervalent iodine compounds were prepared by the reaction of saccharine with (diacetoxyiodo)arenes or acetoxybenziodoxole. Structures of these new imidoiodanes were established by X-ray crystallography. The saccharin-based μ-oxo-bridged imidoiodane readily reacts with silyl enol ethers under mild conditions to give the corresponding α-aminated carbonyl compounds in moderate yields.
- Subjects
IODINE compounds; SACCHARIN; ELECTROPHILES; AROMATIC compounds; X-ray crystallography; ENOL ethers; CARBONYL compounds
- Publication
Chemistry - A European Journal, 2015, Vol 21, Issue 14, p5328
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201500335