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- Title
A New Approach to the Justification of the Wolkenstein-Ptitsyn Formula for the Parameter of the Vitrification Equation.
- Authors
Sanditov, D. S.; Mantatov, V. V.
- Abstract
Abstract: An extended interpretation of the Wolkenstein-Ptitsyn formula for temperature band δTg, characterizing a range of transition from liquid to glass, is considered using the Razumovskaya-Bartenev concept. The derivation of this formula proposed by the authors does not depend on the specific type of temperature dependence of relaxation time. For silicate glasses, calculation δTg by this formula agrees with the calculation by the Williams-Landel-Ferry relation and with the left side of glass transition equation qτg = δTg, where q is the cooling rate and τg is relaxation time. Based on the experimental data, the calculation of parameters of the Razumovskaya-Bartenev equation for silicate glasses and amorphous polymers is carried out for the first time.
- Subjects
VITRIFICATION; SILICATES; GLASS transitions; POLYMERS; TEMPERATURE effect
- Publication
Technical Physics, 2018, Vol 63, Issue 12, p1749
- ISSN
1063-7842
- Publication type
Article
- DOI
10.1134/S1063784218120174