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- Title
Organo(organooxo)mercury(II) chemistry — Synthesis and structure of methyl(phenoxo)mercury(II).
- Authors
Canty, Allan J.; Devereux, Janette W.; Skelton, Brian W.; White, Allan H.
- Abstract
Methyl(phenoxo)mercury(II) may be obtained from the reaction of methyl(chloro)mercury(II) with silver(I) oxide, followed by addition of phenol. The dominant motif of the structure is a pair of independent MeHgOPh aggregates (Hg—C,O 2.05(2) Å, 2.06(1) Å (x2); C-Hg-O 176.6(5)°, 176.3(5)°) loosely associated about a quasi-inversion centre by Hg···O interactions (2.702(9) Å, 2.719(9) Å) to form a dimer (Hg-O-Hg′ 106.0(4)°, 106.5(4)°; O-Hg-O′ 73.0(3)°, 72.6(3)°), the dimer stacking up the short crystallographic c axis (= 6.914(1) Å) at spacings c/2. Vibrational spectroscopic studies are insensitive to the associative interactions.
- Subjects
MERCURY; METHYLMERCURY; ORGANOMERCURY compounds; PHENOL; CRYSTALLOGRAPHY
- Publication
Canadian Journal of Chemistry, 2006, Vol 84, Issue 2, p77
- ISSN
0008-4042
- Publication type
Article
- DOI
10.1139/V05-219