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- Title
A Novel Three-Dimensional Coordination Polymer Involving Pb—Pb Interactions and Three Different Hemidirected Lead(II) Coordination Spheres: X-Ray Crystal Structure of Tris(1,10-phenanthroline-κN1,κN10)bis[{μ3-[5-(sulfo-κO)benzene-1,3-dicarboxylate(3−)-κO1,κO1′ : κO2,κO2′ : κO2]}trilead (Pb—Pb) Trihydrate ([Pb3(phen)3(H2O)2(sip)2]n⋅3 4;H2O)
- Authors
Hong-Ping Xiao; Ali Morsali
- Abstract
A novel 3D polymeric PbII complex involving three different hemidirected PbII coordination spheres, [Pb3(phen)3(H2O)2(sip)2]n⋅3 4;H2O (phen=1,10-phenanthroline and sip=5-sulfoisophthalate=5-sulfobenzene-1,3-dicarboxylate), was synthesized and characterized by elemental analysis and IR spectroscopy. Its single-crystal X-ray structure shows three types of Pb2+ ions with coordination number six for Pb(1) and seven for Pb(2) and Pb(3). Two of the lead atoms, Pb(1) and Pb(3), are involved in Pb—Pb interactions.
- Publication
Helvetica Chimica Acta, 2005, Vol 88, Issue 9, p2543
- ISSN
0018-019X
- Publication type
Article