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- Title
A practical chlorination of tert -butyl esters with PCl<sub>3</sub> generating acid chlorides.
- Authors
Wu, Xiaofang; Zhou, Lei; Yang, Ruoqi; Guo, Fengzhe; Tang, Zi-Long; Xiao, Jing
- Abstract
For the first time, using PCl3, a range of tert -butyl esters is chlorinated successfully, allowing access of both aromatic acid chlorides and aliphatic acid chlorides in good yields. The method features simple reaction conditions and wide substrate scope. Various tert -butyl esters including aryl esters, alkenyl esters, and alkyl esters were tolerated well in the reaction. A plausible mechanism is proposed.
- Subjects
ACYL chlorides; ARYL esters; CHLORINATION; ESTERS
- Publication
Journal of Chemical Research, 2020, Vol 44, Issue 5/6, p301
- ISSN
1747-5198
- Publication type
Article
- DOI
10.1177/1747519819898142