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- Title
The Kinetics of the Reaction of Carbon Dioxide with Propylene Oxide Catalyzed by a Chromium-Salen Complex.
- Authors
Chukanova, O. M.; Belov, G. P.
- Abstract
The kinetics of the reaction of CO2 with propylene oxide utilizing a salenCrCl/PPNCl active catalytic system is studied with varying reaction conditions (temperature, pressure, and cocatalyst/catalyst ratio). The reaction proceeds selectively to form cyclic propylene carbonate (PC) at [PPNCl]/[salenCrCl] ratios above two. The value of the effective activation energy of PC formation is found.
- Subjects
CARBON dioxide; PROPYLENE oxide; CHROMIUM catalysts; METAL complexes; ACTIVATION energy; TEMPERATURE effect
- Publication
Kinetics & Catalysis, 2018, Vol 59, Issue 3, p262
- ISSN
0023-1584
- Publication type
Article
- DOI
10.1134/S0023158418030059