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- Title
Ring-opening metathesis polymerization (ROMP) of fullerene-containing monomers in the presence of a first-generation Grubbs catalyst.
- Authors
Biglova, Yu.; Mustafin, A.; Torosyan, S.; Biglova, R.; Miftakhov, M.
- Abstract
New norbornene-type monomers containing covalently bound C60 fullerene have been obtained. In the presence of the 1st generation Grubbs catalyst [(PCy)ClRuCHPh] (Cy is cyclohexyl), these monomers smoothly undergo homopolymerization and copolymerization with parent fullerene-free monomers. The homopolymers are insoluble in common organic solvents, while the copolymers obtained at different molar ratios to their fullerene-free analogues are very soluble in organic solvents and can be suitable for the preparation of thin films.
- Subjects
RING-opening polymerization; METATHESIS reactions; MONOMERS; FULLERENES; ORGANIC solvents; THIN films
- Publication
Kinetics & Catalysis, 2017, Vol 58, Issue 2, p111
- ISSN
0023-1584
- Publication type
Article
- DOI
10.1134/S0023158417020021