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- Title
Prostanoids: LXXXVI. Synthesis and Reductive Transformations of 2-Chloro-4,4-ethylenedioxy-3-phenylsulfanyl-2-cyclopentenone.
- Authors
Ivanova, N. A.; Khusainova, A. A.; Shangiraeva, F. G.; Akhmetvaleev, R. R.; Miftakhov, M. S.
- Abstract
The reduction of 2-chloro-4,4-ethylenedioxy-3-phenylsulfanyl-2-cyclopentenone with sodium tetra-hydridoborate in ethanol yields 3-chloro-4-hydroxy-2-phenylsulfanyl-2-cyclopentenone, while with the use of lithium aluminum hydride in tetrahydrofuran or the system Zn/NH4Cl in methanol products of more profound reduction are obtained.
- Subjects
PROSTANOIDS; EICOSANOIC acid derivatives; TETRAHYDROFURAN; LITHIUM; ALUMINUM; HYDRIDES
- Publication
Russian Journal of Organic Chemistry, 2003, Vol 39, Issue 10, p1489
- ISSN
1070-4280
- Publication type
Article
- DOI
10.1023/B:RUJO.0000010567.22691.a5