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- Title
Synthesis and Characterization of Sulfonated Poly(Phenylene) Containing a Non-Planar Structure and Dibenzoyl Groups.
- Authors
Hohyoun Jang; Sabuj Chandra Sutradhar; Jiho Yoo; Jaeseong Ha; Jaeseung Pyo; Chaekyun Lee; Taewook Ryu; Whangi Kim
- Abstract
Polymers for application as sulfonated polyphenylene membranes were prepared by nickel-catalyzed carbon-carbon coupling reaction of bis(4-chlorophenyl)-1,2-diphenylethylene (BCD) and 1,4-dichloro-2,5-dibenzoylbenzene (DCBP). Conjugated cis/trans isomer (BCD) had a non-planar conformation containing four peripheral aromatic rings that facilitate the formation of ππ interactions. 1,4-Dichloro-2,5-dibenzoylbenzene was synthesized from the oxidation reaction of 2,5-dichloro-p-xylene, followed by Friedel-Crafts reaction with benzene. DCBP monomer had good reactivity in polymerization affecting the activity of benzophenone as an electron-withdrawing group. The polyphenylene was sulfonated using concentrated sulfuric acid. These polymers without any ether linkages on the polymer backbone were protected from nucleophilic attack by hydrogen peroxide, hydroxide anion, and radicals generated by polymer electrolyte membrane fuel cell (PEMFC) operation systems. The mole fraction of the sulfonic acid groups was controlled by varying the mole ratio of bis(4-chlorophenyl)-1,2-diphenylethylene in the copolymer. In comparison with Nafion 211® membrane, these SBCDCBP membranes showed ion exchange capacity (IEC) ranging from 1.04 to 2.07 meq./g, water uptake from 36.5% to 69.4%, proton conductivity from 58.7 to 101.9 mS/cm, and high thermal stability.
- Subjects
POLYMERS; CHEMICAL synthesis; PROTONS; SULFONIC acids; ISOMERS
- Publication
Energies (19961073), 2016, Vol 9, Issue 2, p115
- ISSN
1996-1073
- Publication type
Article
- DOI
10.3390/en9020115