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- Title
Crystal and molecular structure of trans-[RhCl(CO)(P<sup>t</sup>Bu<sub>2</sub>Ph)<sub>2</sub>].
- Authors
Mayer, Peter; Böttcher, Hans-Christian
- Abstract
Treatment of THF solutions containing the rhodium(II) complex trans-[RhCl2(PtBu2Ph)2] (1) with [Fe2(CO)9] in the same solvent resulted in the formation of the Vaska-type complex trans-[RhCl(CO)(PtBu2Ph)2] (2) in high yield. The title complex 2 was obtained as pale yellow crystals, characterized by NMR and IR spectroscopy, as well as by microanalyses. Additionally, the molecular structure of 2 has been established by X-ray crystallography. As often reported for similar constituted compounds, the chlorido and carbonyl ligands in crystals of 2 are strongly disordered.
- Subjects
MOLECULAR structure; SOLVENTS; NUCLEAR magnetic resonance spectroscopy; X-ray crystallography; LIGANDS (Chemistry)
- Publication
Zeitschrift für Naturforschung B: A Journal of Chemical Sciences, 2018, Vol 73, Issue 12, p1029
- ISSN
0932-0776
- Publication type
Article
- DOI
10.1515/znb-2018-0163