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- Title
Nanosized Vanadium Diboride: Synthesis, Structure, and Properties.
- Authors
Kravchenko, S. E.; Burlakova, A. G.; Domashnev, I. A.; Vinokurov, A. A.; Shilkin, S. P.
- Abstract
X-ray diffraction, scanning electron microscopic, and X-ray photoelectron spectroscopic examinations, as well as energy dispersive X-ray and elemental analyses revealed the formation of single-phase VB2 with the average particle sizes of 20–35 nm from the reaction between vanadium(III) chloride and sodium borohydride at a molar ratio of 1: 10 in the temperature range of 595–930°C in an argon atmosphere at a contact time of 14–28 h. The reaction between amorphous boron and vanadium powders at 800°C in an argon atmosphere at a contact time of 32 h in Na2B4O7 and KCl ionic melts gave VB2 with the average particle size of ~90 nm.
- Subjects
VANADIUM compounds synthesis; NANOPARTICLES; PARTICLE size distribution; SODIUM borohydride; MECHANICAL chemistry
- Publication
Russian Journal of General Chemistry, 2019, Vol 89, Issue 4, p641
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363219040017