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- Title
Spectrophotometric study of dehalogenation of benzyl halides with nickel in aprotic dipolar solvents in the presence of oxygen.
- Authors
Egorov, А.; Novikova, А.; Stepanova, Е.
- Abstract
Oxidative dissolution of nickel in the benzyl halogenide - dipolar aprotic solvent system in the presence of air oxygen proceeds with the formation of benzaldehyde, benzyl alcohol, 1,2-diphenylethane, and trace amounts of 4,4'-ditolyl. Spectrophotometry studies have revealed that the oxidation products are formed in the solution rather than at the nickel surface. It has been shown that the oxygen adsorbed at the nickel surface practically does not pass into the solution.
- Subjects
NICKEL; BENZYL halides; DEHALOGENATION; SPECTROPHOTOMETRY; OXYGEN
- Publication
Russian Journal of General Chemistry, 2016, Vol 86, Issue 2, p251
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363216020079