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- Title
Promoting alkylation of non-transition metals with organic halides in the presence of binary systems based on organometallic compound and transition metal compound: II. Comparative study of efficiency of various agents in the course of destruction of passivating film on the surface of alkylated metal
- Authors
Eremeev, I.
- Abstract
It has been demonstrated that alkylzinc halides efficiently destroy the passivating film on the zinc-copper pair in the course of its alkylation with ethyl bromide to give ethylzinc bromide. The alkylzinc halides efficiency is comparable to that of ethyl iodide and exceeds that of salts of transition or non-transition metals as well as of ultraviolet irradiation. Addition of alkylzinc halides or metal salts as well as ultraviolet irradiation have practically no effect on the developed reaction. The results have demonstrated that the organometallic component of the binary systems is polyfunctional; this permits a generalization of known features of a number of known methods promoting direct synthesis of organometallic compounds.
- Subjects
ALKYLATION; HALIDES; HALOGEN compounds; ORGANOMETALLIC compounds; ORGANIC synthesis; CHEMICAL reactions; ETHYL bromide
- Publication
Russian Journal of General Chemistry, 2014, Vol 84, Issue 10, p1909
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363214100077