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- Title
Electrochemical reduction of 4-methyl-4-(trichloromethyl)cyclohexa-2,5-dien-1-one.
- Authors
Moiseeva, A.; Gavrilova, G.; Vykhodtseva, L.; Nikolaeva, S.; Krut'ko, D.; Beloglazkina, E.
- Abstract
The properties of 4-methyl-4-(trichloromethyl)cyclohexa-2,5-dien-1-one which contains the trichloromethyl substituent at a quaternary carbon atom have been studied by cyclic voltammetry, rotating disk electrode voltammetry, and preparative electrolysis. Reductive dehalogenation involves initial two-electron reductive elimination of one of the geminal chlorine atoms followed by consecutive addition of proton, simultaneous elimination of the two residual halogen atoms to form carbene, and rearrangement of cyclohexadienone into the corresponding 4-methylcyclohepta-2,4,6-trien-1-one.
- Subjects
TRICHLOROMETHYL group; CYCLOHEXYLAMINE; CYCLOHEXADIENONES; TROPONES; LACTONES; ORGANIC synthesis
- Publication
Russian Journal of General Chemistry, 2014, Vol 84, Issue 6, p1074
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363214060036