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- Title
An Improved Model for Molar Volumes of Ti-Carbide, Ti-Nitride and Ti-Carbo-Nitride.
- Authors
Zhang, Huaqing; Du, Yong; Kaptay, George
- Abstract
Molar volume of titanium carbonitride is modelled as function of composition and temperature by two-sublattice model Ti1(C, N, Va)1. Deviations from the ideal solution model in Ti–TiX sections were modelled by regular solution model between X atoms and vacancies in the (X, Va) sublattice. The combined binary models can describe molar volumes of ternary Ti carbonitrides reasonably well without introducing any ternary parameters, proving a good physics behind the binary models.
- Subjects
MOLECULAR volume; TITANIUM; PHYSICS
- Publication
Metallurgical & Materials Transactions. Part A, 2024, Vol 55, Issue 6, p1728
- ISSN
1073-5623
- Publication type
Article
- DOI
10.1007/s11661-024-07395-8