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- Title
Reagent-Free C−H/N−H Cross-Coupling: Regioselective Synthesis of N-Heteroaromatics from Biaryl Aldehydes and NH<sub>3</sub>.
- Authors
Zhao, Huai ‐ Bo; Liu, Zhan ‐ Jiang; Song, Jinshuai; Xu, Hai ‐ Chao
- Abstract
An unprecedented synthesis of N-heteroaromatics from biaryl aldehydes and NH3 through reagent-free C−H/N−H cross-coupling has been developed. The electrosynthesis uses NH3 as an inexpensive and atom-economic nitrogen donor, requires no oxidizing agents, and allows efficient and regioselective access to a wide range of phenanthridines and structurally related polycyclic N-heteroaromatic products.
- Subjects
ALDEHYDE synthesis; REGIOSELECTIVITY (Chemistry); CHEMICAL reagents; ARYL group; OXIDIZING agents
- Publication
Angewandte Chemie, 2017, Vol 129, Issue 41, p12906
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201707192