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- Title
Direct Synthesis of Pyrroles by Dehydrogenative Coupling of Diols and Amines Catalyzed by Cobalt Pincer Complexes.
- Authors
Daw, Prosenjit; Chakraborty, Subrata; Garg, Jai Anand; Ben ‐ David, Yehoshoa; Milstein, David
- Abstract
Herein, the first example of base-metal-catalyzed dehydrogenative coupling of diols and amines to selectively form functionalized 1,2,5-substituted pyrroles liberating water and hydrogen gas as the sole by-products is presented. The reaction is catalyzed by pincer complexes of earth-abundant cobalt.
- Subjects
DEHYDROGENATION; COUPLING reactions (Chemistry); CHEMICAL synthesis; PYRROLES; GLYCOLS; AMINES; COBALT
- Publication
Angewandte Chemie, 2016, Vol 128, Issue 46, p14585
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201607742