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- Title
Regio- and Stereoselective Functionalizations of Tricyclo [3.3.0.0<sup>2,8</sup>]octan-3-one, a Potential Synthon for Polycyclopentanoid Terpenes and Prostacyclin Analogs. Preliminary Communication.
- Authors
Demuth, Martin; Chandrasekhar, Sosale; Nakano, Koichi; Raghavan, Palaykotai R.; Schaffner, Kurt
- Abstract
Chemical transformation of tricyclo [3.3.0.02,8]octan-3-one (1) have been carried out in order to explore its potential utility as a versatile synthon for polycyclopentanoid terpenes and prostacyclin analogs. Various functionalizations of rings A and B and annulation of a third ring C were achieved in generally high yields. The system provides for a large measure of regio- and stereoselective reaction control.
- Publication
Helvetica Chimica Acta, 1980, Vol 63, Issue 8, p2440
- ISSN
0018-019X
- Publication type
Article
- DOI
10.1002/hlca.19800630837