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- Title
Solvation and coordination interactions of tetrapyridylporphyrin in aqueous solutions. Thermal stability.
- Authors
Berezina, N.; Berezin, M.; Minh, Do; Bazanov, M.
- Abstract
The results from application of calorimetric method for studying the energetics of the interparticle interaction in aqueous solutions of tetrapyridylporphyrin have been discussed. The influence of the nature of functional substitution, isomerism of the molecule on the enthalpies of dissolution and complexation with copper and zinc cations by tetrapyridylporphyrin derivatives has been elucidated. The thermal stability of crystalline samples of tetrapyridylporphyrin compounds under atmospheric oxygen conditions has been evaluated.
- Subjects
MOLECULAR structure of porphyrins; AQUEOUS solutions; ANALYTICAL chemistry; MACROCYCLIC compounds; CATIONS; ISOMERISM; MOLECULAR dynamics
- Publication
Russian Journal of General Chemistry, 2017, Vol 87, Issue 3, p639
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363217030422