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- Title
Organic Ionic Plastic Crystals and Low Viscosity Ionic Liquids Based on the Dicyano(nitroso)methanide Anion.
- Authors
Janikowski, Judith; Razali, Mohd R.; Batten, Stuart R.; MacFarlane, Douglas R.; Pringle, Jennifer M.
- Abstract
A new family of organic ionic materials of the dicyano(nitroso)methanide anion is reported. Six of the compounds are room-temperature ionic liquids with low viscosities, which is a physical property highly desired for many synthetic and electrochemical applications. In addition, use of dimethylpyrrolidinium and tetramethylammonium cations yield the first reported dicyano(nitroso)methanide organic ionic plastic crystals, which have an advantageously wide plastic phase region. The salts also exhibit good conductivities and thermal stabilities thus making them suitable as liquid or solid-state electrolytes for a range of electrochemical devices.
- Subjects
PLASTIC crystals; IONIC liquids; TEMPERATURE effect; ELECTROCHEMISTRY; SOLID state chemistry; ELECTROLYTES; THERMAL analysis
- Publication
ChemPlusChem, 2012, Vol 77, Issue 11, p1039
- ISSN
2192-6506
- Publication type
Article
- DOI
10.1002/cplu.201200211