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- Title
Iridium Catalysts with Chiral Bicyclic Pyridine-Phosphane Ligands for the Asymmetric Hydrogenation of Olefins.
- Authors
Quan, Xu; Parihar, Vijay Singh; Bera, Milan; Andersson, Pher G.
- Abstract
New bicyclic pyridine-phosphane ligands were prepared, and their iridium complexes were evaluated in asymmetric hydrogenation of trisubstituted olefins with non-coordinating and weakly coordinating substituents. The iridium catalysts showed high reactivity and enantioselectivity for both types of olefins.
- Subjects
IRIDIUM catalysts; LIGANDS (Chemistry); ENANTIOSELECTIVE catalysis; ALKENE synthesis; REACTIVITY (Chemistry); CHEMICAL reactions
- Publication
European Journal of Organic Chemistry, 2014, Vol 2014, Issue 1, p140
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201301141