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Title
Metal-Rich Copper Chalcogenide Clusters at the Border Between Molecule and Bulk Phase: The Structures of [Cu<sub>93</sub>Se<sub>42</sub>(SeC<sub>6</sub>H<sub>4</sub>SMe)<sub>9</sub>(PPh<sub>3</sub>)<sub>18</sub>], [Cu<sub>96</sub>Se<sub>45</sub>(SeC<sub>6</sub>H<sub>4</sub>SMe)<sub>6</sub>(PPh<sub>3</sub>)<sub>18</sub>], and [Cu<sub>136</sub>S<sub>56</sub>(SCH<sub>2</sub>C<sub>4</sub>H<sub>3</sub>O)<sub>24</sub>(dpppt)<sub>10</sub>]