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- Title
Highly Enantioselective [3+2] Cycloaddition of Vinylcyclopropane with Nitroalkenes Catalyzed by Palladium(0) with a Chiral Bis( tert-amine) Ligand.
- Authors
Wei, Feng; Ren, Chuan ‐ Li; Wang, Dong; Liu, Li
- Abstract
An enantioselective [3+2] cycloaddition of vinyl cyclopropane derived from 1,3-indanedione with nitroalkenes catalyzed by palladium(0) with a chiral bis( tert-amine) ligand was developed in high yields with good diastereoselectivities and excellent enantioselectivities. The resulting bis( tert-amine)-palladium complex proved to be a highly efficient catalyst for this cycloaddition.
- Subjects
VINYLCYCLOPROPANES; NITROALKENES; PALLADIUM; CATALYSIS; RING formation (Chemistry); CYCLOPROPANE; METAL complexes
- Publication
Chemistry - A European Journal, 2015, Vol 21, Issue 6, p2335
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201405407